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51.
The reconstruction of former mountain glaciers has long been used to examine the implications of rapid climate shifts, for example at the last glacial–interglacial transition, and for evaluating asynchronous behaviour of mountain glaciers compared with mid‐latitude ice sheets during the Late Quaternary. Glacier reconstruction has also been used as a source of palaeoclimatic information, based on the recognition of empirical relationships between glaciers and climate. This paper reviews the application and implications of a recently revised method of glacier reconstruction (Carr and Coleman, 2007 ), based around glaciological principles of mass‐balance. This study examines how this approach can be used to test geomorphological interpretations of former mountain glaciation and also to infer precipitation fields at sites of former glaciation. Sites of Younger Dryas niche and icefield glaciation in the British Isles demonstrate how this method can verify interpretations of marginal glaciation and begin to understand the different behaviour of outlet glaciers within the same environmental regime. Examination of a site of former niche glaciation in Southern Africa demonstrates how glacier reconstruction may be used to infer annual and seasonal precipitation values and strongly supports the idea that winter precipitation in Lesotho and SE South Africa was substantially greater than present‐day values during the last glacial cycle. Copyright © 2010 John Wiley & Sons, Ltd.  相似文献   
52.
Climate change and high magnitude mass wasting events pose adverse societal effects and hazards, especially in alpine regions. Quantification of such geomorphic processes and their rates is therefore critical but is often hampered by the lack of appropriate techniques and the various spatiotemporal scales involved in these studies. Here we exploit both in situ cosmogenic beryllium-10 (10Be) and carbon-14 (14C) nuclide concentrations for deducing exposure ages and tracing of sediment through small alpine debris flow catchments in central Switzerland. The sediment cascade and modern processes we track from the source areas, through debris flow torrents to their final export out into sink regions with cosmogenic nuclides over an unprecedented five-year time series with seasonal resolution. Data from a seismic survey and a 90 m core revealed a glacially overdeepened basin, filled with glacial and paraglacial sediments. Surface exposure dating of fan boulders and radiocarbon ages constrain the valley fill from the last deglaciation until the Holocene and show that most of the fan existed in early Holocene times already. Current fan processes are controlled by episodic debris flow activity, snow (firn) and rock avalanches. Field investigations, digital elevation models (DEMs) of difference and geomorphic analysis agree with sediment fingerprinting with cosmogenic nuclides, highlighting that the bulk of material exported today at the outlet of the subcatchments derives from the lower fans. Cosmogenic nuclide concentrations steadily decrease from headwater sources to distal fan channels due to the incorporation of material with lower nuclide concentrations. Further downstream the admixture of sediment from catchments with less frequent debris flow activity can dilute the cosmogenic nuclide signals from debris flow dominated catchments but may also reach thresholds where buffering is limited. Consequently, careful assessment of boundary conditions and driving forces is required when apparent denudation rates derived from cosmogenic nuclide analysis are upscaled to larger regions. © 2018 John Wiley & Sons, Ltd.  相似文献   
53.
Understanding the interactions of vegetation and soil water under varying hydrological conditions is crucial to aid quantitative assessment of land-use sustainability for maintaining water supply for humans and plants. Isolating and estimating the volume and ages of water stored within different compartments of the critical zone, and the associated fluxes of evaporation, transpiration, and groundwater recharge, facilitates quantification of these soil–plant-water interactions and the response of ecohydrological fluxes to wet and dry periods. We used the tracer-aided ecohydrological model EcH2O-iso to examine the response of water ages of soil water storage, groundwater recharge, evaporation, and root-uptake at a mixed land use site, in northeastern Germany during the drought of 2018 and in the following winter months. The approach applied uses a dynamic vegetation routine which constrains water use by ecological mechanisms. Two sites with regionally typical land-use types were investigated: a forested site with sandy soils and a deep rooting zone and a grassland site, with loamier soils and shallower rooting zone. This results in much younger water ages (<1 year) through the soil profile in the forest compared to the grass, coupled with younger groundwater recharge. The higher water use in the forest resulted in a more pronounced annual cycle of water ages compared to the more consistent water age in the loamier soil of the grasslands. The deeper rooting zone of the forested site also resulted in older root-uptake water usage relative to soil evaporation, while the grassland site root-uptake was similar to that of soil evaporation. Besides more dynamic water ages in the forest, replenishment of younger soil waters to soil storage was within 6 months following the drought (cf. >8 months in the grassland). The temporal evaluation of the responsiveness of soil and vegetation interactions in hydrologic extremes such as 2018 is essential to understand changes in hydrological processes and the resilience of the landscape to the longer and more severe summer droughts predicted under future climate change.  相似文献   
54.
Mathematical Geosciences - We present an application of deep generative models in the context of partial differential equation constrained inverse problems. We combine a generative adversarial...  相似文献   
55.
56.
Re-equilibration processes of natural H2O–CO2–NaCl-rich fluid inclusions quartz are experimentally studied by exposing the samples to a pure H2O external fluid at 600 °C. Experimental conditions are selected at nearly constant pressure conditions (309 MPa) between fluid inclusions and pore fluid, with only fugacity gradients in H2O and CO2, and at differential pressure conditions (394–398 MPa, corresponding to an internal under-pressure) in addition to similar CO2 fugacity gradients and larger H2O fugacity gradients. Modifications of fluid inclusion composition and density are monitored with changes in ice dissolution temperature, clathrate dissolution temperature and volume fraction of the vapour phase at room temperature. Specific modification of these parameters can be assigned to specific processes, such as preferential loss/gain of H2O and CO2, or changes in total volume. A combination of these parameters can clearly distinguish between modifications according to bulk diffusion or deformation processes. Bulk diffusion of CO2 according to fugacity gradients is demonstrated at constant pressure conditions. The estimated preferential loss of H2O is not in accordance with those gradients in both constant pressure and differential pressure experiments. The development of deformation halos in quartz around fluid inclusions that are either under-pressurized or over-pressurized promotes absorption of H2O from the inclusions and inhibits bulk diffusion according to the applied fugacity gradients.  相似文献   
57.
Phase analysis of incrustations retrieved from chimney deposits of a combined heat and power plant in Malchow/Germany by X-ray powder diffraction gave evidence for the existence of a previously unknown hydrous calcium magnesium nitrate. Optical investigations of the sample showed the presence of colorless platy crystals with a maximum diameter of about 250 μm embedded in a partly polycrystalline and partly glassy matrix. Aided by EDX-analysis and Raman spectroscopy, a single-crystal diffraction study performed at ambient conditions demonstrated that the material represents a phase with composition Ca2Mg(NO3)6×12H2O. Basic crystallographic data are as follows: trigonal symmetry, space group type R \( \overline{3} \) , a?=?10.5583(5) Å, c?=?19.5351(10) Å, V?=?1885.97(16) Å3, Z?=?3, (R(|F|) = 0.0248). The magnesium ions are coordinated by water molecules to form distorted Mg(H2O)6-octahedra. The calcium atoms are surrounded by nine ligands. The resulting CaO9 tricapped trigonal prisms involve oxygen atoms from additional water moieties as well as from three different bidentate nitrate groups, respectively. Hydrogen bonds link one octahedron with two adjacent prisms into trimers. The trimers in turn are stacked in columns running parallel to [001]. Further hydrogen bonding between neighboring columns results in the formation of a three-dimensional network. To our best knowledge, Ca2Mg(NO3)6×12H2O represents a new structure type. However, column-like topologies with rods consisting of different types of polyhedra have been also observed in other trigonal hydrous nitrates. The structural relationships between these compounds are discussed. It is interesting to note that in previous phase equilibrium studies on the ternary system Ca(NO3)2-Mg(NO3)2-H2O no other hydrous double salt has been described. Finally, the results of the structure analysis allowed a qualitative and quantitative phase analysis of the crystalline part of the chimney deposit by the Rietveld method.  相似文献   
58.
We synthesize reaction rims between thermodynamically incompatible phases in the system MgO-Al2O3-SiO2 applying uniaxial load using a creep apparatus. Synthesis experiments are done in the MgO-SiO2 and in the MgO-Al2O3 subsystems at temperatures ranging from 1150 to 1350 °C imposing vertical stresses of 1.2 to 29 MPa at ambient pressure and under a constant flow of dry argon. Single crystals of synthetic and natural quartz and forsterite, synthetic periclase and synthetic corundum polycrystals are used as starting materials. We produce enstatite rims at forsterite-quartz contacts, enstatite-forsterite double rims at periclase-quartz contacts and spinel rims at periclase-corundum contacts. We find that rim growth under the “dry” conditions of our experiments is sluggish compared to what has been found previously in nominally “dry” piston cylinder experiments. We further observe that the nature of starting material, synthetic or natural, has a major influence on rim growth rates, where natural samples are more reactive than synthetic ones. At a given temperature the effect of stress variation is larger than what is anticipated from the modification of the thermodynamic driving force for reaction due to the storage of elastic strain energy in the reactant phases. We speculate that this may be due to modification of the physical properties of the polycrystals that constitute the reaction rims or by deformation under the imposed load. In our experiments rim growth is very sluggish at forsterite-quartz interfaces. Rim growth is more rapid at periclase-quartz contacts. The spinel rims that are produced at periclase-corundum interfaces show parabolic growth indicating that reaction rim growth is essentially diffusion controlled. From the analysis of time series done in the MgO-Al2O3 subsystem we derive effective diffusivities for the Al2O3 and the MgO components in a spinel polycrystal as ${\rm D}_{MgO} = 1.4 \pm 0.2 \cdot 10^{-15}$  m2/s and ${\rm D}_{Al_2O_3} = 3.7 \pm 0.6 \cdot 10^{-16}$  m2/s for T?=?1350 °C and a vertical stress of 2.9 MPa.  相似文献   
59.
What can reasonably be expected from the UNFCCC process and the climate conference in Paris 2015? To achieve transformative change, prevailing unsustainable routines embedded in socio-economic systems have to be translated into new and sustainable ones. This article conceptualizes the UNFCCC and the associated policy processes as a catalyst for this translation by applying a structurational regime model. This model provides an analytical distinction of rules (norms and shared meaning) and resources (economic resources as well as authoritative and allocative power) and allows us to conceptualize agency on various levels, including beyond nation states. The analysis concludes that the UNFCCC's narrow focus on emission targets, which essentially is a focus on resources, has proven ineffective. In addition, the static division of industrialized and developing countries in the Convention's annexes and the consensus-based decision-making rules have impeded ambitious climate protection. The article concludes that the UNFCCC is much better equipped to provide rules for climate protection activities and should consciously expand this feature to improve its impact.

Policy relevance

The international community is negotiating a new global climate agreement, to be adopted at the Conference of the Parties (COP 21) in December 2015 in Paris and to be applicable from 2020. This article analyses the successes and limitations the UNFCCC has had so far in combating climate change and it develops recommendations on how to enhance efforts within and beyond the framework of the Convention. From our analysis we derive two main recommendations for an effective and structurationally balanced treaty: First, multidimensional mitigation contributions going beyond emission targets could strongly improve countries’ abilities to tailor their contributions around national political discourses. Second, the UNFCCC regime should be complemented with another treaty outside of the UNFCCC framework. This ‘Alliance of the Ambitious’ would allow the pioneers of climate protection to move ahead and enjoy the benefits of cooperation. The dynamics generated through such a club approach could be fed back into the UNFCCC, leading to increased ambition by others in future commitment cycles.  相似文献   
60.
Replacement of olivine by orthopyroxene is a frequently observed phenomenon in mantle metasomatism. In order to study element redistribution in SiO2 metasomatism we synthesised orthopyroxene reaction rims at the contacts between forsterite-rich olivine and quartz. The orthopyroxene rims grew from the original quartz-olivine interface into both directions implying counterdiffusion of iron/magnesium and silicon. Following local equilibrium partitioning the XFe is lower in the orthopyroxene than in the reactant olivine at the olivine-orthopyroxene replacement front. The resulting local iron excess is compensated by formation of orthopyroxene with a higher XFe at the quartz-orthopyroxene interface, which is out of equilibrium with the reactant olivine. This is facilitated through short circuit diffusion along grain boundaries within the orthopyroxene rim. Due to the low capacity of orthopyroxene to accommodate Ni, this component is forced to diffuse back into the olivine producing a Ni enriched zone ahead of the replacement front. This leads to Ni contents in the orthopyroxene rim, which are higher than what is expected in equilibrium with the unaltered olivine. Taking quartz as a proxy for a silica rich fluid or liquid metasomatising agent, we conclude that the overall element fractionation between olivine and the silica rich phase may deviate from equilibrium partitioning so that the Fe and Ni concentrations in the orthopyroxene which is in contact with quartz are higher than in equilibrium with the reactant olivine. This indicates that kinetic fractionation is important for the chemical evolution of both the mantle rocks and the metasomatising agents.  相似文献   
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